Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts
Identifieur interne : 000248 ( France/Analysis ); précédent : 000247; suivant : 000249Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyanine-hydrotalcite catalysts
Auteurs : I. Chatti [Tunisie] ; A. Ghorbel [Tunisie] ; P. Grange [Belgique] ; J. M. Colin [France]Source :
- Catalysis today [ 0920-5861 ] ; 2002.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.
Affiliations:
- Belgique, France, Tunisie
- Gouvernorat de Tunis, Province du Brabant wallon, Région wallonne
- Louvain-la-Neuve, Tunis
- Université catholique de Louvain
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Pascal:02-0429724Le document en format XML
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<term>Catalytic reaction</term>
<term>Cobalt complex</term>
<term>Experimental study</term>
<term>Heterogeneous catalysis</term>
<term>Hydrotalcite</term>
<term>Intercalation compound</term>
<term>Metallophthalocyanine</term>
<term>Organic ligand</term>
<term>Oxidation</term>
<term>Sulfides</term>
<term>Thiol</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Hydrotalcite</term>
<term>Cobalt complexe</term>
<term>Coordinat organique</term>
<term>Phtalocyanine métallique</term>
<term>Réaction catalytique</term>
<term>Oxydation</term>
<term>Thiol</term>
<term>Sulfure</term>
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<front><div type="abstract" xml:lang="en">Three Mg-Al hydrotalcites containing cobalt(II) phthalocyanine were prepared by direct synthesis, anion exchange and structure reconstruction. Differences in physicochemical properties and mechanical resistance were observed. The results of the mercaptan oxidation reaction were compared to those obtained with an industrial non-basic impregnated active charcoal. An important activity difference in favor of the prepared catalysts was obtained, confirming that the adequate tuning of basic and oxidant properties lead to a promising catalyst.</div>
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